As a young man in Prussia, Hermann Walther Nernst
(1864-1941) expressed his ambition to become a poet. In 1883, he
had graduated first in his class at the Gymnasium of Graudenz (currently
part of Poland), where his studies focused on classical literature,
humanities and natural science. Thirty-seven years later, he was
awarded the Nobel Prize for chemistry in honor of his work in chemical
thermodynamics. The man who adored the words of Shakespeare created
poetry of a different meter when he bridged the quantum theory of
Planck with the dynamics of chemical processes.
Walther Nernst was the son of a civil servant.
He studied in Zurich, Wurzburg and Graz. At Graz, he worked with
von Ettinghausen, with whom he published work in 1886 which formed
part of the experimental foundation of the modern electronic theory
of metals. He took his Ph.D at Wurzburg, beginning his career as
a physicist. His transition to chemistry began in Leipzig but developed
fully in his subsequent position as an associate professor of physics
of Gottingen. In 1905, he was appointed professor of physical chemistry
in Berlin. He became director of the Physikalisch-Technisches Reichsanstalt
in 1922 and finally professor of physics at Berlin in 1924 before
retiring in 1933.
Nernst’s first outstanding
work was his theory of the electromotive force of the voltaic cell
(1888). He developed methods for measuring dielectric constants
and was the first to show that solvents of high dielectric constants
promote the ionization of substances. Nernst proposed the theory
of solubility product, generalized the distribution law, and offered
a theory of heterogeneous reactions. In 1906, his heat theorem became
the Third Law of Thermodynamics. This theorem garnered the Nobel
Prize but his research encompassed a far broader scope, including
photochemistry, electrochemistry and studies of high temperature
gases.
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